EMSA has published a report which analyses hydrogen’s main characteristics to frame which safety hazards, system threats and risks to be considered and mitigated when using hydrogen as ship fuel.
The purpose of the report is to assist the industry and the regulators towards a safe and harmonised deployment of this relevant technology that could demonstrate an important step towards decarbonisation of the sector. According to EMSA, hydrogen, when used as ship fuel, presents the following significant safety hazards and risks due to its unique properties:
Flammability and explosiveness
Hydrogen’s wide flammability range and lower ignition energy compared to methane make it highly flammable and prone to more severe explosions. Its higher burning velocity can escalate explosions into detonations, posing greater risks than natural gas.
Storage and distribution challenges
The low boiling point of hydrogen complicates its storage and distribution. Managing boil-off gas and preventing the condensation of gases like nitrogen and oxygen are critical to avoid equipment malfunction and potential explosion hazards.
Density and dispersion
Hydrogen’s low density causes it to rise and disperse quickly in open environments. In confined spaces, such as within a ship, it can accumulate in high spots, increasing the risk of ignition from sources like ceiling lights. Designing safety measures, such as gas detectors and ventilation systems, must account for hydrogen’s density and behavior in leak scenarios.
Pressure effects
High-pressure storage of hydrogen (250-700 bar) creates potential energy that, upon release, can cause significant pressure effects even without combustion. Sudden releases from high-pressure systems can ignite spontaneously, posing immediate risks to personnel and equipment.
Hazards in confined spaces
Hydrogen releases in confined ship spaces amplify explosion pressures rapidly, potentially damaging structures and leading to further leakage. Leakages of liquefied hydrogen (LH2) can induce cooling effects that compromise gas-tight integrity and safety equipment function, further complicating emergency responses.
Material compatibility and embrittlement
Hydrogen can adversely affect metal properties through embrittlement, reducing structural integrity. Condensed oxygen-enriched air can increase material flammability upon contact, necessitating careful material selection and design considerations.
Health and safety risks
Finally, EMSA notes that significant hydrogen leakages pose risks of asphyxiation due to oxygen depletion, alongside risks of frostbites and burn injuries due to low temperatures and reduced flame visibility.
Source: Safety4sea
